The local environment of Ga, Se and Tl atoms in InTe-based solid solutions was studied by EXAFS technique. It was shown that all investigated atoms are substitutional impurities, which enter the In(1), Te and In(2) positions in the InTe structure, respectively. The electrical measurements revealed the In1-xGaxTe and InTe1-xSex solid solutions become semiconductors at x>0.24 and >0.15, respectively.Keywords: X-ray absorption spectroscopy, synchrotron radiation, local environment, semiconductor solid solutions, indium gallium telluride, indium telluride selenide, indium thallium telluride, structure